WebBis (iodomethyl)mercury (ICH 2) 2 Hg, an effective transfer agent of one CH 2 group in Simmons–Smith type reactions, was synthesized in 80% yield by sequential treatment of diethylzinc with CH 2 I 2 and HgBr 2 < 92JOM (438)11 > and in 75% yield by the reaction of ethyl (iodo)zinc with CH 2 I 2 followed by HgCl 2 < 82JIC111 >. (103)

Diethylzinc - Welcome to the NIST WebBook

WebFormula: C 4 H 10 Zn Molecular weight: 123.50 IUPAC Standard InChI: InChI=1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3; IUPAC Standard InChIKey: … WebIUPAC Standard InChIKey: HQWPLXHWEZZGKY-UHFFFAOYSA-N Copy CAS Registry Number: 557-20-0 Chemical structure: This structure is also available as a 2d Mol file; … perle bleue martinique

Syntheses of Novel Chiral Sulfinamido Ligands and Their …

WebTo a solution of diethylzinc (ca. 1mol/L in hexane, 2.9 mL, 2.9 mmol) and tridecafluorohexyl iodide (0.92 mL, 4.2 mmol) in DMPU (1.2 mL) was added ethyl 2-Iodobenzoate (500 mg, 1.9 mmol) and copper(I) iodide (37 mg, 0.20 mmol) and the reaction mixture was stirred under nitrogen at 90 °C for 16 hours. The reaction was quenched with 4 mol/L HCl ... WebDiethylzinc. Diethylzinc addition to the enone 200 was achieved with a chiral monodentate phosphoramidite ligand and copper triflate, followed by cyclopropanation of the zinc … WebCauses severe skin burns and eye damage. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects. Suspected of damaging fertility. Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. Catches fire spontaneously if exposed to air. perleche et carence